Aging resistance of zinc neodecanoate in rubber products

2024-06-27by admin

As an important organic zinc compound, zinc neodecanoate plays a key role in the processing and performance improvement of rubber products, especially in enhancing the aging resistance of rubber products. Aging resistance refers to the ability of rubber materials to resist performance degradation under the action of external environmental factors such as heat, light, oxygen, ozone, mechanical stress, etc. This is crucial for extending the service life of rubber products. Zinc neodecanoate provides multiple protections for rubber products through its unique mechanism of action. Its specific contribution to the aging resistance of rubber products will be discussed in depth below from several dimensions.

1. Antioxidant and anti-ozone effects
Rubber is susceptible to oxidation and ozone attack in the natural environment, causing molecular chain breakage and thus affecting its physical properties. As an antioxidant and anti-ozonant, zinc neodecanoate can effectively capture and neutralize free radicals and slow down the aging process of rubber. The presence of zinc ions can form stable coordination compounds, inhibit the peroxidation reaction of rubber molecular chains, thereby reducing cracks caused by aging and maintaining the elasticity and strength of rubber products. Especially under dynamic use conditions, such as tires, conveyor belts and other applications, the protective effect of zinc neodecanoate is more significant.

2. Stabilizer function
In rubber formulations, zinc neodecanoate not only acts as an active agent to promote the vulcanization reaction, but also acts as a stabilizer to prevent excessive cross-linking during the vulcanization process. Excessive cross-linking will increase the brittleness of the rubber and reduce its fatigue resistance and service life. Adding an appropriate amount of zinc neodecanoate can optimize the structure of the vulcanization network, allowing the rubber to improve its dynamic mechanical properties and aging resistance while maintaining sufficient cross-linking density.

3. Prevent metal catalytic aging
Rubber products often contain metal parts or contact metal surfaces. Metal ions such as iron and copper can catalyze the aging process of rubber. Zinc neodecanoate forms a protective film covering the metal surface, preventing the catalytic effect of metal ions and reducing the breakage of rubber molecular chains caused by metal ions, thereby effectively delaying the aging process. This feature is particularly important in rubber products such as tires and seals that need to be closely matched with metal.

4. Improve processing performance
During rubber processing, zinc neodecanoate can also improve the mixing and vulcanization process, improve the fluidity and uniformity of rubber, which indirectly improves the aging resistance of the product. Good processing properties help to form a uniform vulcanization network and avoid local overheating or under-vulcanization areas, which are often the starting point of aging.

5. Light stability and weather resistance
Rubber products used outdoors, such as roofing materials, window seals, etc., face challenges from ultraviolet radiation. Although the main function of zinc neodecanoate is not to directly absorb ultraviolet rays, it can work synergistically with other light stabilizers to protect rubber from ultraviolet damage, slow down the photoaging process, and keep the color and mechanical properties of rubber products stable.

Conclusion
In summary, the application of zinc neodecanoate in rubber products not only improves the aging resistance of rubber, but also takes into account the processing performance and the overall performance of the product. By inhibiting oxidation, ozone attack, metal catalytic aging, and improving vulcanization network structure and processing conditions, zinc neodecanoate has become an indispensable additive for improving the durability and service life of rubber products. In the future, with in-depth research on the aging mechanism of rubber and increasing environmental protection requirements, the optimization and innovative applications of zinc neodecanoate and its derivatives will be more extensive, bringing continuous technological progress and product upgrades to the rubber industry.
Further reading:

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Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh

Bis[2-(N,N-dimethylamino)ethyl] ether

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